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アクセス権	open access
URI	https://hdl.handle.net/2115/71555
タイトル	Formation of bismuth-core-carbon-shell nanoparticles by bismuth immersion during plasma CVD synthesis of thin diamond films
著者	Takahiro, Tamura ; Takuya, Takami ; Sachiko, Kobayashi ; Taro, Nagahama ; Takashi, Yanase ; Toshihiro, Shimada
著者名 Takahiro, Tamura
著者名 Takuya, Takami
著者名 Sachiko, Kobayashi
著者名 Taro, Nagahama
著者名 Takashi, Yanase
e-Rad_Researcher 10262148 著者名 Toshihiro, Shimada
言語	英語
発行日	2016-10
出版者	Elsevier
収録物名	Diamond & Related Materials
巻(号)	69
ページ	127-132
抄録	This paper describes an attempt to synthesize bismuth-doped diamond by plasma CVD. Solid bismuth was inserted into the reaction plasma of CH4 and H2. Examination by TEM showed that most of the bismuth was included as Bi nanoparticles in the carbon nanospheres, which segregated at the grain boundary of the diamond polycrystals. Diffraction peaks corresponding to the carbon allotrope Chaoite were observed at the grain boundaries. The Raman spectra showed very complex features between 100-1600 cm-1, suggesting the existance of molecule-like species.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
権利情報	© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
PISSN	0925-9635
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1016/j.diamond.2016.07.015

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