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論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/72089
タイトル	Carbon dioxide and water: An effective multiphase medium for selective hydrogenation of nitriles with a Pd/Al2O3 catalyst
著者	Bhosale, Ashvini ; Yoshida, Hiroshi ; Fujita, Shin-ichiro ; Arai, Masahiko
著者名 Bhosale, Ashvini
e-Rad_Researcher 20027410 著者名 Yoshida, Hiroshi
e-Rad_Researcher 80156869 著者名 Fujita, Shin-ichiro
e-Rad_Researcher 60125490 著者名 Arai, Masahiko
言語	英語
キーワード	Multiphase media
	Selective hydrogenation
	Nitriles
	Selectivity control
	Water
発行日	2016-12
出版者	Elsevier
収録物名	Journal of CO2 Utilization
巻(号)	16
ページ	371-374
抄録	The effectiveness of a multiphase medium including CO2 and water was studied for the selective hydrogenation of various nitriles of 2-phenylethyl cyanide (PEC), cinnamonitrile, n-hexanenitrile (HN) and 4-cyanobiphenyl with a conventional Pd/Al2O3 catalyst. Such a multiphase reaction medium was observed to have different impacts changing from one nitrile to another and the selective production of primary amine was achieved with PEC and HN but not with the other nitriles. Possible reasons for the substrate-dependent effects of CO2 and water were discussed.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
権利情報	© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
PISSN	2212-9820
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1016/j.jcou.2016.09.006

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