Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts

Moromi, Sondomoyee K.; Siddiki, S. M. A. H.; Kon, Kenichi; Toyao, Takashi; Shimizu, Ken-ichi

Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts

Moromi, Sondomoyee K.; Siddiki, S. M. A. H.; Kon, Kenichi et al.

Catalysis today, 2017, 281, 507-511

Permalink : https://hdl.handle.net/2115/72825

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アクセス権	open access
URI	https://hdl.handle.net/2115/72825
タイトル	Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts
著者	Moromi, Sondomoyee K. ; Siddiki, S. M. A. H. ; Kon, Kenichi ; Toyao, Takashi ; Shimizu, Ken-ichi
著者名 Moromi, Sondomoyee K.
著者名 Siddiki, S. M. A. H.
著者名 Kon, Kenichi
e-Rad_Researcher 80775388 著者名 Toyao, Takashi
e-Rad_Researcher 60324000 著者名 Shimizu, Ken-ichi
言語	英語
キーワード	Pt nanoparticles
	Dehydrogenation
	N-heterocycles
	Hydrogen storage
発行日	2017-03-01
出版者	Elsevier
収録物名	Catalysis today
巻(号)	281
ページ	507-511
抄録	Pt metal nanoparticles loaded on various supports and carbon-supported various metal catalysts are tested for dehydrogenation of 6-methyl-1,2,3,4- tetrahydroquinoline to 6-methyl-quinoline under oxidant-free conditions. In the 20 types of the catalysts screened, carbon-supported Pt catalyst (Pt/C) shows the highest activity. Pt/C is reusable after the reaction and is effective for dehydrogenation of various N-heterocycles (tetrahydroquinolines and indoline). Pt/C is also effective for hydrogenation of quinoline under 3 bar H-2. The results demonstrate that this catalytic method may be useful for an organic hidride-based hydrogen storage system.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
権利情報	© 2016 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
PISSN	0920-5861
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1016/j.cattod.2016.06.027