open access

https://hdl.handle.net/2115/75634

Phosphorous Partition in Dephosphorization Slag Occurring with Crystallization at Initial Stage of Solidification

日本語

hot thermocouple

2009-03-01

日本鉄鋼協会

鉄と鋼

95(3)

241-250

Basicity and the amount of FetO were investigated for their effects on the crystallization behavior of the simulated dephosphorizing slags. Twelve kinds of slags were prepared (C/S=1.0–2.5, FetO=10–20%, P2O5=5%). In the present experiment, the Hot Thermocouple Technique was used to melt and quench the samples. After quenching, the microstructure of the slag and the distributions of elements were examined by SEM and EDS analysis. The diameter of the crystal which precipitated in the sample increased with increasing basicity (C/S) and decreasing FetO content. In addition, glassy regions were observed in the two samples whose FetO content was 20% and whose basicity was 1.0 or 1.5. The samples (10% FetO, 5% P2O5), whose basicity was 1.0 (sample-1) precipitated as a monocalcium silicate (CaO·SiO2); the sample (10% FetO, 5% P2O5) whose basicity was 1.5 (sample-4) precipitated as a dicalcium silicate (2CaO·SiO2). In higher FetO (15–20%) slags, the crystals of the solid solution between 3CaO·P2O5 and 2CaO·SiO2 ((C3P–C2S)ss) were observed. When the amount of CaO increased from C/S=1.5 to C/S=2.5, 2CaO·SiO2 appeared with phosphorous content, but phosphorous was not found in CaO·SiO2.

学術雑誌論文

Version of Record

著作権は日本鉄鋼協会にある

0021-1575

1883-2954

AN00151251