Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis

Jamil, Md A. R.; Siddiki, S. M. A. Hakim; Touchy, Abeda Sultana; Rashed, Md Nurnobi; Poly, Sharmin Sultana; Jing, Yuan; Ting, Kah Wei; Toyao, Takashi; Maeno, Zen; Shimizu, Ken-ichi

Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis

Jamil, Md A. R.; Siddiki, S. M. A. Hakim; Touchy, Abeda Sultana et al.

ChemSusChem, 2019, 12(13), 3115-3125

Permalink : https://hdl.handle.net/2115/78814

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アクセス権	open access
URI	https://hdl.handle.net/2115/78814
タイトル	Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis
著者	Jamil, Md A. R. ; Siddiki, S. M. A. Hakim ; Touchy, Abeda Sultana ; Rashed, Md Nurnobi ; Poly, Sharmin Sultana ; Jing, Yuan ; Ting, Kah Wei ; Toyao, Takashi ; Maeno, Zen ; Shimizu, Ken-ichi
著者名 Jamil, Md A. R.
著者名 Siddiki, S. M. A. Hakim
著者名 Touchy, Abeda Sultana
著者名 Rashed, Md Nurnobi
著者名 Poly, Sharmin Sultana
著者名 Jing, Yuan
著者名 Ting, Kah Wei
e-Rad_Researcher 80775388 著者名 Toyao, Takashi
e-Rad_Researcher 30721154 著者名 Maeno, Zen
e-Rad_Researcher 60324000 著者名 Shimizu, Ken-ichi
言語	英語
キーワード	amidation
	amination
	biomass
	heterogeneous catalysis
	triglycerides
発行日	2019-07-05
出版者	Wiley-Blackwell
収録物名	ChemSusChem
巻(号)	12(13)
ページ	3115-3125
抄録	The use of triglycerides as an important class of biomass is an effective strategy to realize a more sustainable society. Herein, three heterogeneous catalytic methods are reported for the selective one-pot transformation of triglycerides into value-added chemicals: i) the reductive amination of triglycerides into fatty amines with aqueous NH3 under H-2 promoted by ZrO2-supported Pt clusters; ii) the amidation of triglycerides under gaseous NH3 catalyzed by high-silica H-beta (H beta) zeolite at 180 degrees C; iii) the H beta-promoted synthesis of nitriles from triglycerides and gaseous NH3 at 220 degrees C. These methods are widely applicable to the transformation of various triglycerides (C-4-C-18 skeletons) into the corresponding amines, amides, and nitriles.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This is the peer reviewed version of the following article: Md. A. R. Jamil Dr. S. M. A. Hakim Siddiki Dr. Abeda Sultana Touchy Md. Nurnobi Rashed Sharmin Sultana Poly Yuan Jing Kah Wei Ting Dr. Takashi Toyao Dr. Zen Maeno Prof. Dr. Ken-ichi Shimizu, Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis, ChemSusChem 2019, 12, 3115, which has been published in final form at https://doi.org/10.1002/cssc.201900365 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
PISSN	1864-5631
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1002/cssc.201900365