Two-Photon-Induced [2+2] Cycloaddition of Bis-thymines: A Biocompatible and Reversible Approach

Ricci, Monica; Rutten, Martin G. T. A.; Toyouchi, Shuichi; Nanayakkara, Sepa; Fortuni, Beatrice; Vitale, Raffaele; Rocha, Susana; Wilson, Daniela A.; Hofkens, Johan; Saito, Kei; Uji-I, Hiroshi

Two-Photon-Induced [2+2] Cycloaddition of Bis-thymines: A Biocompatible and Reversible Approach

Ricci, Monica; Rutten, Martin G. T. A.; Toyouchi, Shuichi et al.

ACS Omega, 2020, 5(20), 11547-11552

Permalink : https://hdl.handle.net/2115/78933

このアイテムのアクセス数:641件（2026-10-17 19:13 集計）

閲覧可能ファイル

ファイル	フォーマット	サイズ	閲覧回数	説明
https://doi.org/10.1021/acsomega.0c00770			48

論文情報

ファイル出力 EndNote Basic出力 Mendeley出力

アクセス権	open access
URI	https://hdl.handle.net/2115/78933
タイトル	Two-Photon-Induced [2+2] Cycloaddition of Bis-thymines: A Biocompatible and Reversible Approach
著者	Ricci, Monica ; Rutten, Martin G. T. A. ; Toyouchi, Shuichi ; Nanayakkara, Sepa ; Fortuni, Beatrice ; Vitale, Raffaele ; Rocha, Susana ; Wilson, Daniela A. ; Hofkens, Johan ; Saito, Kei ; Uji-I, Hiroshi
著者名 Ricci, Monica
著者名 Rutten, Martin G. T. A.
著者名 Toyouchi, Shuichi
著者名 Nanayakkara, Sepa
著者名 Fortuni, Beatrice
著者名 Vitale, Raffaele
著者名 Rocha, Susana
著者名 Wilson, Daniela A.
著者名 Hofkens, Johan
著者名 Saito, Kei
e-Rad_Researcher 40519352 著者名 Uji-I, Hiroshi
言語	英語
発行日	2020-05-26
出版者	American Chemical Society
収録物名	ACS Omega
巻(号)	5(20)
ページ	11547-11552
抄録	Despite having great value across a wide variety of scientific fields, two-photon polymerizations currently suffer from two significant problems: the need for photoinitiators, which generate toxic side products, and the irreversibility of the process. Hence, the design of a versatile approach that circumvents these issues represents a major scientific challenge. Herein, we report a two-photon absorption strategy where reversible [2 + 2] cycloaddition of bis-thymines was achieved without the need for any photoinitiator. The cycloaddition and cycloreversion reactions could be induced by simply changing the irradiation wavelength, and repeated writing and erasing cycles were performed. The simplicity, reversibility, and biocompatibility of this strategy open up a whole new toolbox for applications across a wide variety of scientific fields.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
権利情報	Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
権利情報	Copyright © 2020 American Chemical Society
PISSN	2470-1343
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1021/acsomega.0c00770