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アクセス権	open access
URI	https://hdl.handle.net/2115/79862
タイトル	meso-Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for Ni-II Ions
著者	Mori, Daiki ; Yoneda, Tomoki ; Suzuki, Masaaki ; Hoshino, Tyuji ; Neya, Saburo
著者名 Mori, Daiki
e-Rad_Researcher 60756055 著者名 Yoneda, Tomoki
著者名 Suzuki, Masaaki
著者名 Hoshino, Tyuji
著者名 Neya, Saburo
言語	英語
キーワード	Expanded Porphyrins
	Macrocyclic Complexes
	NNNO Ligand
	Porphyrins
	Tripyrrinone
発行日	2019-12-02
出版者	Wiley-Blackwell
収録物名	Chemistry-an asian journal
巻(号)	14(23)
ページ	4169-4173
抄録	We report expanded porphyrins with pyridine rings and two neighboring carbonyl groups, which allow Ni-II ions to coordinate to the tripyrrinone-type NNNO coordination structure with Ni-O bonds. The selectivity of tripyrrinone is superior to other pyrrolic or pyridinic cavities of expanded porphyrins. Introduction of alpha-carbonyl pyridine next to the tripyrrolic conjugated structure is a powerful strategy for regioselective metalation of flexible expanded porphyrinoids.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This is the peer reviewed version of the following article: Daiki Mori, Tomoki Yoneda, Masaaki Suzuki, Masaaki Tyuji Hoshino, Saburo Neya, Saburo meso‐Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for NiII Ions, Chemistry An Asian J., which has been published in final form at [https://onlinelibrary.wiley.com/doi/full/10.1002/asia.201901375]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
PISSN	1861-4728
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1002/asia.201901375

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