Air- and moisture-stable Xantphos-ligated palladium dialkyl complex as a precatalyst for cross-coupling reactions

Takahashi, Rina; Kubota, Koji; Ito, Hajime

Chemical communications, 2020, 56(3), 407-410

Permalink : https://hdl.handle.net/2115/80131

このアイテムのアクセス数:499件（2026-08-26 08:18 集計）

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revised manuscript (56.3)	pdf	612 KB	1,144

アクセス権	open access
URI	https://hdl.handle.net/2115/80131
タイトル	Air- and moisture-stable Xantphos-ligated palladium dialkyl complex as a precatalyst for cross-coupling reactions
著者	Takahashi, Rina ; Kubota, Koji ; Ito, Hajime
著者名 Takahashi, Rina
著者名 Kubota, Koji
e-Rad_Researcher 90282300 著者名 Ito, Hajime
言語	英語
発行日	2020-01-11
出版者	Royal Society of Chemistry
収録物名	Chemical communications
巻(号)	56(3)
ページ	407-410
抄録	Although xantphos has been employed in a variety of palladium-catalyzed cross-coupling reactions, there has been little progress in developing Xantphos-ligated precatalysts. In this report, we describe a Xantphos-ligated palladium dialkyl complex that acts as a powerful precatalyst for C-N, C-S, and C-C cross-coupling reactions. This precatalyst is air- and moisture stable but can be thermally activated in the absence of external reagents. Additionally, potential catalyst inhibitors are not generated during the precatalyst activation. This complex thus represents a convenient alternative to previously reported classes of Xantphos-ligated precatalysts.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	1359-7345
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1039/c9cc06946a