Morphology Control and Metallization of Porous Polymers Synthesized by Michael Addition Reactions of a Multi-Functional Acrylamide with a Diamine

Naga, Naofumi; Ito, Minako; Mezaki, Aya; Tang, Hao-Chun; Chang, Tso-Fu Mark; Sone, Masato; Nageh, Hassan; Nakano, Tamaki

Morphology Control and Metallization of Porous Polymers Synthesized by Michael Addition Reactions of a Multi-Functional Acrylamide with a Diamine

Naga, Naofumi; Ito, Minako; Mezaki, Aya et al.

Materials, 2021, 14(4), 800

Permalink : https://hdl.handle.net/2115/81035

このアイテムのアクセス数:599件（2026-08-12 05:09 集計）

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アクセス権	open access
URI	https://hdl.handle.net/2115/81035
タイトル	Morphology Control and Metallization of Porous Polymers Synthesized by Michael Addition Reactions of a Multi-Functional Acrylamide with a Diamine
著者	Naga, Naofumi ; Ito, Minako ; Mezaki, Aya ; Tang, Hao-Chun ; Chang, Tso-Fu Mark ; Sone, Masato ; Nageh, Hassan ; Nakano, Tamaki
e-Rad_Researcher 40314538 著者名 Naga, Naofumi
著者名 Ito, Minako
著者名 Mezaki, Aya
著者名 Tang, Hao-Chun
e-Rad_Researcher 10647069 著者名 Chang, Tso-Fu Mark
e-Rad_Researcher 30323752 著者名 Sone, Masato
著者名 Nageh, Hassan
e-Rad_Researcher 40227856 著者名 Nakano, Tamaki
言語	英語
キーワード	porous polymer
	Michael addition reaction
	acryl amide
	diamine
	electroless plating
発行日	2021-02-09
出版者	MDPI
収録物名	Materials
巻(号)	14(4)
ページ	800
抄録	Porous polymers have been synthesized by an aza-Michael addition reaction of a multi-functional acrylamide, N,N′,N″,N‴-tetraacryloyltriethylenetetramine (AM4), and hexamethylene diamine (HDA) in H2O without catalyst. Reaction conditions, such as monomer concentration and reaction temperature, affected the morphology of the resulting porous structures. Connected spheres, co-continuous monolithic structures and/or isolated holes were observed on the surface of the porous polymers. These structures were formed by polymerization-induced phase separation via spinodal decomposition or highly internal phase separation. The obtained porous polymers were soft and flexible and not breakable by compression. The porous polymers adsorbed various solvents. An AM4-HDA porous polymer could be plated by Ni using an electroless plating process via catalyzation by palladium (II) acetylacetonate following reduction of Ni ions in a plating solution. The intermediate Pd-catalyzed porous polymer promoted the Suzuki-Miyaura cross coupling reaction of 4-bromoanisole and phenylboronic acid.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
権利情報	Creative Commons Attribution 4.0 International
PISSN	1996-1944
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.3390/ma14040800