Gas sorption of nano-porous supramolecules formed by multi-hydrogen bonded coordination capsules

Tadokoro, Makoto; Machida, Hironobu; Toyofuku, Ryuji; Murakami, Megumi; Kamebuchi, Hajime; Isoda, Kyosuke; Kobayashi, Fumiya; Takahashi, Kiyonori; Noro, Shin'ichiro; Nakamura, Takayoshi

Gas sorption of nano-porous supramolecules formed by multi-hydrogen bonded coordination capsules

Tadokoro, Makoto; Machida, Hironobu; Toyofuku, Ryuji et al.

Chemical communications, 2021, 57(18), 2249-2252

Permalink : https://hdl.handle.net/2115/81198

このアイテムのアクセス数:572件（2026-08-19 03:38 集計）

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https://doi.org/10.1039/d0cc07869g			27

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アクセス権	open access
URI	https://hdl.handle.net/2115/81198
タイトル	Gas sorption of nano-porous supramolecules formed by multi-hydrogen bonded coordination capsules
著者	Tadokoro, Makoto ; Machida, Hironobu ; Toyofuku, Ryuji ; Murakami, Megumi ; Kamebuchi, Hajime ; Isoda, Kyosuke ; Kobayashi, Fumiya ; Takahashi, Kiyonori ; Noro, Shin'ichiro ; Nakamura, Takayoshi
e-Rad_Researcher 60249951 著者名 Tadokoro, Makoto
著者名 Machida, Hironobu
著者名 Toyofuku, Ryuji
著者名 Murakami, Megumi
著者名 Kamebuchi, Hajime
e-Rad_Researcher 20568620 著者名 Isoda, Kyosuke
e-Rad_Researcher 90884205 著者名 Kobayashi, Fumiya
e-Rad_Researcher 90812595 著者名 Takahashi, Kiyonori
e-Rad_Researcher 70373347 著者名 Noro, Shin'ichiro
e-Rad_Researcher 60270790 著者名 Nakamura, Takayoshi
言語	英語
発行日	2021-03-04
出版者	Royal Society of Chemistry
収録物名	Chemical communications
巻(号)	57(18)
ページ	2249-2252
抄録	[{Re-I(CO)(3)(Hbim)}(3)(tpta)](2) (1, Hbim(-) = 2,2'-biimidazolate monoanion, tpta = 2,4,6-tripyridyl-1,3,5-triazine) was prepared as a nano-space supramolecule by using a new group of H-bonded coordination capsules. The hamburger bun-shaped half unit [{Re-I(CO)(3)(Hbim)}(3)(tpta)] contains six intermolecular H-bonds of Hbim(-) ligands with complementary dual NH center dot center dot center dot N types, and three [Re-I(CO)(3)(Hbim)] are coordinated by bridging tridentate tpta. Interestingly, mechanical grinding easily would convert single crystals of 1 to an amorphous state with minor crystallinity while maintaining the nano-space pores. The ground sample can reversibly uptake and release small molecules such as CO2 and (CH2Cl)(2).
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
権利情報	Creative Commons Attribution-NonCommercial 3.0 Unported
PISSN	1359-7345
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1039/d0cc07869g