Synthesis and Optical Properties of C,N-Swapped Boranils Derived from Potassium Acyltrifluoroborates

Matsuura, Satsuki; Taguchi, Jumpei; Seki, Tomohiro et al.

Bulletin of the chemical society of Japan, 2021, 94(5), 1547-1552

Permalink : https://hdl.handle.net/2115/82484

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ファイル	フォーマット	サイズ	閲覧回数	説明
https://doi.org/10.1246/bcsj.20210024			24

アクセス権	open access
URI	https://hdl.handle.net/2115/82484
タイトル	Synthesis and Optical Properties of C,N-Swapped Boranils Derived from Potassium Acyltrifluoroborates
著者	Matsuura, Satsuki ; Taguchi, Jumpei ; Seki, Tomohiro ; Ito, Hajime
著者名 Matsuura, Satsuki
著者名 Taguchi, Jumpei
著者名 Seki, Tomohiro
e-Rad_Researcher 90282300 著者名 Ito, Hajime
言語	英語
キーワード	Acylboron compounds
	Boron-containing heterocycles
	Photoluminescence
発行日	2021-05
出版者	日本化学会（Chemical Society of Japan）
収録物名	Bulletin of the chemical society of Japan
巻(号)	94(5)
ページ	1547-1552
抄録	Novel C,O-chelated bora-heterocycles were synthesized. Reaction of potassium acyltrifluoroborates with tetrahydroquinolin-8-ol furnished C,N-swapped boranils in a single step. All five obtained borates showed photoluminescence in solid state. One of them showed yellow-to-orange reversible mechano-chromic luminescence. Further derivatization afforded a B-chiral borate with an O,C, O-tridentate ligand that showed significant thermochromism.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
PISSN	0009-2673
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1246/bcsj.20210024