Pincer-Type Phosphorus Compounds with Boryl-Pendant and Application in Catalytic H-2 Generation from Ammonia-Borane: A Theoretical Study

Yang, Deshuai; Bao, Panqing; Yang, Zhen et al.

ChemCatChem, 2021, 13(18), 3925-3929

Permalink : https://hdl.handle.net/2115/82595

このアイテムのアクセス数:631件（2026-10-07 17:23 集計）

ファイル	フォーマット	サイズ	閲覧回数	説明
https://doi.org/10.1002/cctc.202100661			26

アクセス権	open access
URI	https://hdl.handle.net/2115/82595
タイトル	Pincer-Type Phosphorus Compounds with Boryl-Pendant and Application in Catalytic H-2 Generation from Ammonia-Borane: A Theoretical Study
著者	Yang, Deshuai ; Bao, Panqing ; Yang, Zhen ; Chen, Zhaoxu ; Sakaki, Shigeyoshi ; Maeda, Satoshi ; Zeng, Guixiang
著者名 Yang, Deshuai
著者名 Bao, Panqing
著者名 Yang, Zhen
著者名 Chen, Zhaoxu
著者名 Sakaki, Shigeyoshi
e-Rad_Researcher 60584836 著者名 Maeda, Satoshi
著者名 Zeng, Guixiang
言語	英語
キーワード	ammonia borane
	theoretical study
	dehydrogenation
	pincer-type phosphorus
	phosphorus-boryl cooperation
発行日	2021-09-03
出版者	Wiley-Blackwell
収録物名	ChemCatChem
巻(号)	13(18)
ページ	3925-3929
抄録	Metal-free catalysts composed of heavy main group element(s) have been limited. Herein, a theoretical study unveils that pincer-type phosphorus compound bearing a boryl-pendant is good catalyst for H-2 generation from ammonia borane through phosphorus-boryl (P-B) cooperation function. Pincer-type phosphorus compound without boryl-pendant is not active for this reaction, indicating the important role of the P-B cooperation function.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
PISSN	1867-3880
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1002/cctc.202100661