Synthesis of hydrosilylboronates via the monoborylation of a dihydrosilane Si-H bond and their application for the generation of dialkylhydrosilyl anions

Takeuchi, Takumi; Shishido, Ryosuke; Kubota, Koji et al.

Chemical science, 2021, 12(35), 11799-11804

Permalink : https://hdl.handle.net/2115/82677

このアイテムのアクセス数:667件（2026-08-26 07:19 集計）

ファイル	フォーマット	サイズ	閲覧回数	説明
https://doi.org/10.1039/d1sc01440d			22

アクセス権	open access
URI	https://hdl.handle.net/2115/82677
タイトル	Synthesis of hydrosilylboronates via the monoborylation of a dihydrosilane Si-H bond and their application for the generation of dialkylhydrosilyl anions
著者	Takeuchi, Takumi ; Shishido, Ryosuke ; Kubota, Koji ; Ito, Hajime
著者名 Takeuchi, Takumi
著者名 Shishido, Ryosuke
著者名 Kubota, Koji
e-Rad_Researcher 90282300 著者名 Ito, Hajime
言語	英語
発行日	2021-09-21
出版者	Royal Society of Chemistry
収録物名	Chemical science
巻(号)	12(35)
ページ	11799-11804
抄録	The synthesis of a series of hydrosilylboronates via the selective iridium- or nickel-catalyzed monoborylation of dihydrosilane Si-H bonds is described. The synthesized silylboronates, which bear a single Si-H bond, can be used as novel silicon nucleophiles in the presence of transition-metal catalysts or bases. The first Si-29{H-1} NMR spectroscopic evidence for the formation of (t-Bu)(2)HSiLi, generated by the reaction of (t-Bu)(2)HSi-B(pin) with MeLi, is reported as the first example of a dialkylhydorosilyl lithium species.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
PISSN	2041-6520
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1039/d1sc01440d