Metal-Containing Schiff Base/Sulfoxide Ligands for Pd(II)-Catalyzed Asymmetric Allylic C-H Aminations

Bunno, Youka; Tsukimawashi, Yuta; Kojima, Masahiro; Yoshino, Tatsuhiko; Matsunaga, Shigeki

Metal-Containing Schiff Base/Sulfoxide Ligands for Pd(II)-Catalyzed Asymmetric Allylic C-H Aminations

Bunno, Youka; Tsukimawashi, Yuta; Kojima, Masahiro et al.

ACS catalysis, 2021, 11(5), 2663-2668

Permalink : https://hdl.handle.net/2115/84165

このアイテムのアクセス数:389件（2026-02-07 04:39 集計）

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アクセス権	open access
URI	https://hdl.handle.net/2115/84165
タイトル	Metal-Containing Schiff Base/Sulfoxide Ligands for Pd(II)-Catalyzed Asymmetric Allylic C-H Aminations
著者	Bunno, Youka ; Tsukimawashi, Yuta ; Kojima, Masahiro ; Yoshino, Tatsuhiko ; Matsunaga, Shigeki
著者名 Bunno, Youka
著者名 Tsukimawashi, Yuta
e-Rad_Researcher 90824714 著者名 Kojima, Masahiro
e-Rad_Researcher 50756179 著者名 Yoshino, Tatsuhiko
e-Rad_Researcher 50334339 著者名 Matsunaga, Shigeki
言語	英語
キーワード	asymmetric catalysis
	asymmetric synthesis
	allylic C-H functionalization
	palladium
	Schiff base ligand
発行日	2021-02-12
出版者	American Chemical Society
収録物名	ACS catalysis
巻(号)	11(5)
ページ	2663-2668
抄録	Metal-containing Schiff base/sulfoxides were developed as chiral ligands for Pd(II)-catalyzed asymmetric intramolecular allylic C-H amination reactions. The use of metal-containing Schiff base ligands allows tuning the selectivity and reactivity of the Pd(II)-catalyst, whereby a Schiff base-Cu(II)/sulfoxide ligand in combination with Pd(OAc)(2) showed the best performance. Both internal and terminal alkenes were applicable, and the C-H amination products were obtained in up to 91:9 er.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-DFVJGMK3T9JEWQJWWTJR
PISSN	2155-5435
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1021/acscatal.0c05261