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アクセス権	open access
URI	https://hdl.handle.net/2115/85464
タイトル	Chiral Carboxylic Acid Assisted Enantioselective C-H Activation with Achiral (CpMIII)-M-x (M = Co, Rh, Ir) Catalysts
著者	e-Rad_Researcher 50756179 著者名 Yoshino, Tatsuhiko
	e-Rad_Researcher 50334339 著者名 Matsunaga, Shigeki
言語	英語
キーワード	C-H activation
	asymmetric catalysis
	chiral carboxylic acid
	cobalt
	rhodium
	iridium
発行日	2021-05-17
出版者	American Chemical Society
収録物名	ACS catalysis
巻(号)	11(11)
ページ	6455-6466
抄録	Enantioselective C-H functionalization is a powerful tool for synthesizing chiral molecules. In the past few years, the combination of high-valent group 9 metals with achiral Cp-x ligands and chiral carboxylic acids (CCA) has emerged as a promising catalytic system to enable selective cleavage and functionalization of enantiotopic C-H bonds. This Perspective summarizes the background, catalyst design, and applied reactions in detail, followed by a discussion of future directions.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS catalysis, copyright c American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-JSZYU629QNPSRBXEYQPX.
PISSN	2155-5435
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1021/acscatal.1c01351

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