Protection Strategies for the Conversion of Biobased Furanics to Chemical Building Blocks

Coumans, Ferdy J. A. G.; Overchenko, Zhanna; Wiesfeld, Jan J. et al.

sustainable chemistry & engineering, 2022, 10(10), 3116-3130

Permalink : https://hdl.handle.net/2115/85810

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https://doi.org/10.1021/acssuschemeng.1c06723     42

論文情報

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アクセス権
open access
URI
https://hdl.handle.net/2115/85810
タイトル
Protection Strategies for the Conversion of Biobased Furanics to Chemical Building Blocks
著者
Coumans, Ferdy J. A. G. ; Overchenko, Zhanna ; Wiesfeld, Jan J. ; Kosinov, Nikolay ; Nakajima, Kiyotaka ; Hensen, Emiel J. M.
著者名
Coumans, Ferdy J. A. G.
著者名
Overchenko, Zhanna
著者名
Wiesfeld, Jan J.
著者名
Kosinov, Nikolay
e-Rad_Researcher
90451997
著者名
Nakajima, Kiyotaka
著者名
Hensen, Emiel J. M.
言語
英語
キーワード
Biomass
Chemical building blocks
Furanics
Humins
Side reactions
Protection
発行日
2022
出版者
American Chemical Society
収録物名
sustainable chemistry & engineering
巻(号)
10(10)
ページ
3116-3130
抄録
In recent years, the urgency to replace fossil-based resources by renewablebiomass for obtaining chemical building blocks has only increased. Carbohydrate-derivedfuranic compounds are regarded as promising platforms for a renewable value chain. Thehigh reactivity of such biobased intermediates requires the development of novel catalyticchemistry to enhance product yield. The protection of reactive functional groupsprovides a way to improve the product selectivity. Such protection strategies are commonpractice in the synthesis offine chemicals and pharmaceuticals but are not fully exploredfor the conversion of furanic compounds. In this perspective, several examples ofprotection strategies focusing on the selective passivation of 5-HMF are discussed.Formation and removal of these protection groups are highlighted as well as theapplication of the neutralized 5-HMF in further processing. A guide for selecting theappropriate protection strategy depending on the targeted chemistry and operatingconditions is provided.
資源タイプ
学術雑誌論文
出版タイプ
Version of Record
PISSN
2168-0485
関連情報 (isIdenticalTo)
出版社版DOI
https://doi.org/10.1021/acssuschemeng.1c06723