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論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/87677
タイトル	Cp*Rh-III/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes
著者	Hirose, Jumpei ; Wakikawa, Takumi ; Satake, Shun ; Kojima, Masahiro ; Hatano, Manabu ; Ishihara, Kazuaki ; Yoshino, Tatsuhiko ; Matsunaga, Shigeki
著者名 Hirose, Jumpei
著者名 Wakikawa, Takumi
著者名 Satake, Shun
e-Rad_Researcher 90824714 著者名 Kojima, Masahiro
著者名 Hatano, Manabu
著者名 Ishihara, Kazuaki
e-Rad_Researcher 50756179 著者名 Yoshino, Tatsuhiko
e-Rad_Researcher 50334339 著者名 Matsunaga, Shigeki
言語	英語
キーワード	asymmetric catalysis
	rhodium catalysis
	chiral anion
	oxyamination
	tetrahydrofuran
発行日	2021-12-07
出版者	American Chemical Society
収録物名	ACS catalysis
巻(号)	11(24)
ページ	14702-15251
抄録	The enantioselective intramolecular oxyamination of unsaturated alkoxyamines using a hybrid catalytic system consisting of Cp*Rh-III/chiral disulfonate/CuOAc is described. Tetrahydrofuran derivatives with a tetrasubstituted chiral center were obtained under the optimized conditions in 91:9-97:3 er. The use of a sterically hindered chiral disulfonate and a Cu additive was essential for the high enantioselectivity.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-A6FVH2CV4P9I3PH3RZBV.
PISSN	2155-5435
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1021/acscatal.1c04699

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