Cp*Rh(III)/Boron Hybrid Catalysis for Directed C–H Addition to β-
Substituted α,β-Unsaturated Carboxylic Acids

Tanaka, Ryo; Hirata, Yuki; Kojima, Masahiro et al.

Chemical communications, 2021, 58, 76-79

Permalink : https://hdl.handle.net/2115/87679

このアイテムのアクセス数:272件（2026-10-06 07:20 集計）

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アクセス権	open access
URI	https://hdl.handle.net/2115/87679
タイトル	Cp*Rh(III)/Boron Hybrid Catalysis for Directed C–H Addition to β- Substituted α,β-Unsaturated Carboxylic Acids
著者	Tanaka, Ryo ; Hirata, Yuki ; Kojima, Masahiro ; Yoshino, Tatsuhiko ; Matsunaga, Shigeki
著者名 Tanaka, Ryo
著者名 Hirata, Yuki
e-Rad_Researcher 90824714 著者名 Kojima, Masahiro
e-Rad_Researcher 50756179 著者名 Yoshino, Tatsuhiko
e-Rad_Researcher 50334339 著者名 Matsunaga, Shigeki
言語	英語
発行日	2021-11-29
出版者	Royal Society of Chemistry
収録物名	Chemical communications
巻(号)	58
ページ	76-79
抄録	The C-H bond addition reaction of 2-phenylpyridine derivatives with alpha,beta-unsaturated carboxylic acids catalyzed by Cp*Rh(iii)/BH3 center dot SMe2 is reported. Activation of C-H bonds with the rhodium catalyst and activation of alpha,beta-unsaturated carboxylic acids with the boron catalyst cooperatively work, and a BINOL-urea hybrid ligand significantly improved the reactivity. With the optimized hybrid catalytic system, various beta-disubstituted carboxylic acids were obtained under mild reaction conditions.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	1359-7345
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1039/d1cc05956d