1,2-Disubstituted 1,2-Dihydro-1,2,4,5-tetrazine-3,6-dione as a Dynamic Covalent Bonding Unit at Room Temperature

Kawai, Kentaro; Ikeda, Kazuki; Sato, Akane; Kabasawa, Akira; Kojima, Masahiro; Kokado, Kenta; Kakugo, Akira; Sada, Kazuki; Yoshino, Tatsuhiko; Matsunaga, Shigeki

1,2-Disubstituted 1,2-Dihydro-1,2,4,5-tetrazine-3,6-dione as a Dynamic Covalent Bonding Unit at Room Temperature

Kawai, Kentaro; Ikeda, Kazuki; Sato, Akane et al.

Journal of the American Chemical Society, 2022, 144(3), 1370-1379

Permalink : https://hdl.handle.net/2115/88127

このアイテムのアクセス数:336件（2026-08-25 00:12 集計）

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アクセス権	open access
URI	https://hdl.handle.net/2115/88127
タイトル	1,2-Disubstituted 1,2-Dihydro-1,2,4,5-tetrazine-3,6-dione as a Dynamic Covalent Bonding Unit at Room Temperature
著者	Kawai, Kentaro ; Ikeda, Kazuki ; Sato, Akane ; Kabasawa, Akira ; Kojima, Masahiro ; Kokado, Kenta ; Kakugo, Akira ; Sada, Kazuki ; Yoshino, Tatsuhiko ; Matsunaga, Shigeki
著者名 Kawai, Kentaro
著者名 Ikeda, Kazuki
著者名 Sato, Akane
著者名 Kabasawa, Akira
e-Rad_Researcher 90824714 著者名 Kojima, Masahiro
e-Rad_Researcher 40600226 著者名 Kokado, Kenta
e-Rad_Researcher 10374224 著者名 Kakugo, Akira
e-Rad_Researcher 80225911 著者名 Sada, Kazuki
e-Rad_Researcher 50756179 著者名 Yoshino, Tatsuhiko
e-Rad_Researcher 50334339 著者名 Matsunaga, Shigeki
言語	英語
発行日	2022-01-18
出版者	American Chemical Society
収録物名	Journal of the American Chemical Society
巻(号)	144(3)
ページ	1370-1379
抄録	Dynamic covalent bonds are useful tools in a wide range of applications. Although various reversible chemical reactions have been studied for this purpose, the requirement for harsh conditions, such as high temperature and low or high pH, to activate generally stable covalent bonds limits their potential applications involving biomolecules or household utilization. Here, we report the design, synthesis, characterization, and dynamic covalent bonding properties of 1,2-disubstituted 1,2-dihydro-1,2,4,5-tetrazine-3,6-dione (TETRAD). Hetero-Diels-Alder reactions of TETRAD with furan derivatives and their retro-reactions proceeded rapidly at room temperature under neutral conditions, enabling a chemically induced sol-gel transition system.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-JKCBT3BXPRU3JRJMTVT3.
PISSN	0002-7863
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1021/jacs.1c11665