Solid-state cross-coupling reactions of insoluble aryl halides under polymer-assisted grinding conditions

Kubota, Koji; Seo, Tamae; Ito, Hajime

Faraday discussions, 2023, 241, 104-113

Permalink : https://hdl.handle.net/2115/90134

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ファイル	フォーマット	サイズ	閲覧回数	説明
POLAG_MS_revise	pdf	1.04 MB	274

アクセス権	open access
URI	https://hdl.handle.net/2115/90134
タイトル	Solid-state cross-coupling reactions of insoluble aryl halides under polymer-assisted grinding conditions
著者	Kubota, Koji ; Seo, Tamae ; Ito, Hajime
著者名 Kubota, Koji
著者名 Seo, Tamae
e-Rad_Researcher 90282300 著者名 Ito, Hajime
言語	英語
発行日	2023-01-01
出版者	Royal Society of Chemistry
収録物名	Faraday discussions
巻(号)	241
ページ	104-113
抄録	In this study, polymer-assisted grinding (POLAG), a ball-milling technique based on the use of polymer additives, was applied to mechanochemical solid-state Suzuki-Miyaura cross-coupling reactions of insoluble aryl halides. We found that the efficiency of this challenging solid-state cross-coupling was improved by the addition of polytetrafluoroethylene (PTFE) as a POLAG additive under high-temperature ball-milling conditions. Our results suggest that POLAG is a promising approach for controlling the reactivity of insoluble substrates that are barely reactive under conventional solution-based conditions.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	1359-6640
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1039/d2fd00121g