open access

https://hdl.handle.net/2115/90177

Modulation of electrical and thermal transports through lattice distortion in BaTi1-x Nb x O3 solid solutions

英語

thermoelectrics

2022-07-13

IOP Publishing

Nanotechnology

33(40)

405702

The electron and heat transports in solids are through the movement of carrier electrons and quantized lattice vibrations (phonons), which are sensitive to the lattice distortion and ionized impurities, and are essential aspects for the development of novel thermoelectric materials. In this study, we systematically investigated the modulations of electrical and thermal conductivities of BaTi1-x Nb x O3 solid solution (BTNO, 0 <= x <= 1) epitaxial films. At room temperature, BaTiO3 belongs to tetragonal perovskite and exhibits electron conduction through doubly degenerated Ti 3d-t(2g) orbitals upon doping, while BaNbO3 belongs to cubic perovskite and exhibits metallic electron conduction through partially filled triply degenerate Nb 4d-t(2g) orbitals. By controlling the Ti/Nb ratio, we found a dual modulation effect on both the lattice structures and conduction band, which affects the electrical and thermal conductivities. Similar to the SrTi1-x Nb x O3 solid solution (STNO, 0 <= x <= 1) system, a phase transition was detected at x similar to 0.5, at which both the electron and heat transports exhibit abrupt changes. Unlike the transition in STNO, which was attributed to a polaronic phase transition, the transition in BTNO was due to contributions from both the lattice distortion and polaron effect. By controlling the lattice distortion, conduction band, and polaronic phase transitions, the electrical and thermal conductivity of BTNO epitaxial films are modulated within a much greater range than those of the STNO epitaxial films. Due to the double contribution of electron carriers and phonon to thermal conductivity (kappa), the maximum kappa modulation ratio of BTNO epitaxial films was similar to 6.9. Our research provides an effective route to design electrical/thermal management materials.

学術雑誌論文

Accepted Manuscript

Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International

This is the Accepted Manuscript version of an article accepted for publication in Nanotechnology. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1088/1361-6528/ac78f3

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