Controlled helical senses of twisting in two-, three- and four-layer cyclophanes with planar chirality

Katoono, Ryo; Shimomura, Kai

Chemical communications, 2022, 58(96), 13385-13388

Permalink : https://hdl.handle.net/2115/90941

このアイテムのアクセス数:284件（2026-01-17 01:05 集計）

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Chem. Commun._58(96)_13385-13388	pdf	967 KB	245

アクセス権	open access
URI	https://hdl.handle.net/2115/90941
タイトル	Controlled helical senses of twisting in two-, three- and four-layer cyclophanes with planar chirality
著者	e-Rad_Researcher 60432142 著者名 Katoono, Ryo
著者	著者名 Shimomura, Kai
言語	英語
発行日	2022-12-14
出版者	Royal Society of Chemistry
収録物名	Chemical communications
巻(号)	58(96)
ページ	13385-13388
抄録	We synthesized planar chiral cyclophanes with multiple pairs of helical conformations that were generated by twisting at the interlayer. Three- and four-layer cyclophanes preferred a homochiral form with a single sense of twisting through intramolecular transmission of planar chirality. Alternatively, a heterochiral form was dominant in a two-layer cyclophane consisting of two achiral planes that were stacked orthogonally.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	1359-7345
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1039/d2cc05742e