open access

https://hdl.handle.net/2115/91074

Solid-state luminescence of Au(I) complexes with external stimuli-responsive properties

英語

Crystalline molecular rotors

2021-12-29

Elsevier

Journal of Photochemistry and Photobiology C: Photochemistry Reviews

51

100478

In the last decade, the field of stimuli-responsive luminescent materials have been intensely emerged because of the high potential application to functional sensors or photoelectronic devices. In particular, luminescent molecular crystals constructed from Au(I) complexes have produced a wide range of examples of luminescent alterations when some external stimulations, such as heat, mechanical stress, vapor (or solvents), were applied to the solid samples. In this review, we describe the recent progress through a summary of the reported Au(I) complexes based on their utilized stimuli-responsive mechanisms, which are categorized in crystal phase transitions ("crystal-to-amorphous", "crystal-to-crystal" and "single-crystal-to-single-crystal" transitions) and molecular rotation in crystalline media, respectively.

学術雑誌論文

Accepted Manuscript

Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International

© 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/

1389-5567