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論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/91260
タイトル	Intramolecular [2+2] Cycloaddition of Isocarbostyrils Catalyzed by an Iridium Visible-Light Photocatalyst
著者	e-Rad_Researcher 80282721 著者名 Arai, Noriyoshi
言語	英語
発行日	2023-04-07
出版者	American Chemical Society
収録物名	Journal of organic chemistry
巻(号)	88(7)
ページ	4848-4853
抄録	Irradiation on N-(omega-alkenyl)isocarbostyrils in the presence of an iridium photocatalyst by LEDs emitting 455 nm light gave the corresponding cyclobutane-fused benzo[b]quinolizine derivatives stereoselectively in high yields. Loading 1 mol % of the catalyst was enough to obtain high yields of the products in convenient reaction time in many cases. The reaction likely proceeds through stepwise [2 + 2] cycloaddition via a triplet biradical intermediate.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of organic chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-D8FCZ8PUPYWSQB8WK94K.
PISSN	0022-3263
関連情報	PMID 36895086
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1021/acs.joc.3c00059

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