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論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/91879
タイトル	Cobalt(I)-Catalyzed Reductive Cyclization of Enynes and Diynes Using Hydrogen Gas as a Reductant
著者	著者名 Isoda, Kaho
	e-Rad_Researcher 90226019 著者名 Sato, Yoshihiro
言語	英語
発行日	2023-03-31
出版者	American Chemical Society
収録物名	Organic letters
巻(号)	25(12)
ページ	2103-2107
抄録	Reductive cyclization of enynes and diynes by using H2 gas as a reductant was realized, and the corresponding cyclized products were obtained in good yields without olefin isomerization and over-reduction of the products. By an experiment using D2 instead of H2, it was confirmed that H2 unambiguously operates as a reductant in this reaction. The protocol of the reaction is very economical and user-friendly, using air-and moisture-stable CoBr2 center dot 6H2O and 1 atm of pressure of H2.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-RR5P3TD2XX2QE749UHM7.
PISSN	1523-7060
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1021/acs.orglett.3c00524

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