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アクセス権	open access
URI	https://hdl.handle.net/2115/92583
タイトル	Synthesis of Benzo[c]azepine-1,3(2H)-diones via C−H Alkylation/Cyclization with α,β-Unsaturated Acyl Fluorides
著者	Hosoi, Satoko ; Hirata, Yuki ; Kurihara, Takumaru ; Kojima, Masahiro ; Yoshino, Tatsuhiko ; Matsunaga, Shigeki
著者名 Hosoi, Satoko
著者名 Hirata, Yuki
著者名 Kurihara, Takumaru
e-Rad_Researcher 90824714 著者名 Kojima, Masahiro
e-Rad_Researcher 50756179 著者名 Yoshino, Tatsuhiko
e-Rad_Researcher 50334339 著者名 Matsunaga, Shigeki
言語	英語
キーワード	benzo[c]azepine-1,3(2H)-dione
	C-H activation
	α,β-unsaturated acyl fluoride
	hydroxamate imide
発行日	2023-05-17
出版者	Wiley-Blackwell
収録物名	Asian journal of organic chemistry
巻(号)	12(8)
ページ	e202300218
抄録	Transition-metal-catalyzed directed C-H functionalization reactions are a powerful method to construct N-heterocycles. However, compared to the formation of five- and six-membered rings, that of seven-membered rings has been much less explored. Here, the synthesis of benzo[c]azepine-1,3(2H)-diones is described, which are benzene-fused seven-membered imides, from hydroxamates and α,β-unsaturated acyl fluorides via C-H activation using a Cp*Rh(III) catalyst. Under mild reaction conditions, this reaction affords benzo[c]azepine-1,3(2H)-diones that bear a substituent at the 5-position.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This is the pre-peer reviewed version of the following article: https://onlinelibrary.wiley.com/doi/10.1002/ajoc.202300218, which has been published in final form at 10.1002/ajoc.202300218. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
PISSN	2193-5807
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1002/ajoc.202300218

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