open access

https://hdl.handle.net/2115/93636

Thermoresponsive Lamellar Hydrogels with Tunable Turbidity, Structural Color, and Anisotropic Swelling

英語

smart window

2023-11-29

American Chemical Society(ACS)

ACS Applied Materials & Interfaces

15(49)

57687-57698

We report a thermoresponsive anisotropic photonic hydrogel: poly(dodecyl glyceryl itaconate)/polyacrylamide-poly(N-isopropylacrylamide) hydrogel (PDGI/PAAm-PNIPAM hydrogel). Hydrogels with uniaxially aligned lamellar bilayers possess bright structural color and swelling anisotropy, while PNIPAM-based hydrogels exhibit distinct thermoresponsive properties around a lower critical solution temperature (LCST). Hybridization of thermoresponsive PNIPAM with the lamellar hydrogel can give the anisotropic photonic hydrogel various fascinating thermoresponsive properties, such as structural color/turbid transition, thermoresponsive structural color, and anisotropic deswelling/reswelling behavior by temperature stimuli. The temperature-induced changes in turbidity, structural color, and anisotropic swelling of the gel around the LCST can be tuned by controlling the incorporated PNIPAM density. PNIPAM can be regioselectively incorporated into the specific region of the lamellar hydrogels by photomasking during UV polymerization. The PDGI/PAAm-PNIPAM hydrogel can find diverse promising applications such as smart windows and smart displays.

学術雑誌論文

Accepted Manuscript

This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS applied materials & interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-R5UBAEZNT6DB8HAT4VUW.

1944-8244