Stress-Induced Martensitic Transformation in Na3YCl6

Miura, Akira; Muraoka, Koki; Maki, Kotaro et al.

Journal of the American Chemical Society, 2024, 146(36), 25263-25269

Permalink : https://hdl.handle.net/2115/95904

このアイテムのアクセス数:86件（2026-07-17 20:43 集計）

閲覧可能ファイル 

ファイル フォーマット サイズ 閲覧回数 説明
Na3YCl6_main pdf 1.77 MB 176
Na3YCl6_support pdf 1.20 MB 34

論文情報

ファイル出力 EndNote Basic出力 Mendeley出力

アクセス権
open access
URI
https://hdl.handle.net/2115/95904
タイトル
Stress-Induced Martensitic Transformation in Na3YCl6
著者
Miura, Akira ; Muraoka, Koki ; Maki, Kotaro ; Kawaguchi, Saori ; Hikima, Kazuhiro ; Muto, Hiroyuki ; Matsuda, Atsunori ; Yamane, Ichiro ; Shimada, Toshihiro ; Ito, Hiroaki ; Mizuguchi, Yoshikazu ; Moriyoshi, Chikako ; Nakajima, Hiroshi ; Mori, Shigeo ; Oike, Hiroshi ; Nakayama, Akira ; Sun, Wenhao ; Rosero-Navarro, Nataly Carolina ; Tadanaga, Kiyoharu
e-Rad_Researcher
10603201
著者名
Miura, Akira
e-Rad_Researcher
10912074
著者名
Muraoka, Koki
著者名
Maki, Kotaro
著者名
Kawaguchi, Saori
e-Rad_Researcher
50845617
著者名
Hikima, Kazuhiro
e-Rad_Researcher
20293756
著者名
Muto, Hiroyuki
e-Rad_Researcher
70295723
著者名
Matsuda, Atsunori
著者名
Yamane, Ichiro
e-Rad_Researcher
10262148
著者名
Shimada, Toshihiro
著者名
Ito, Hiroaki
e-Rad_Researcher
50609865
著者名
Mizuguchi, Yoshikazu
e-Rad_Researcher
00325143
著者名
Moriyoshi, Chikako
e-Rad_Researcher
00283151
著者名
Nakajima, Hiroshi
e-Rad_Researcher
20251613
著者名
Mori, Shigeo
著者名
Oike, Hiroshi
e-Rad_Researcher
10422007
著者名
Nakayama, Akira
著者名
Sun, Wenhao
著者名
Rosero-Navarro, Nataly Carolina
e-Rad_Researcher
90244657
著者名
Tadanaga, Kiyoharu
言語
英語
キーワード
martensitic transformation
uniaxial pressure
volume expansion
monoclinic
rhombohedral
ternary sodium chloride
発行日
2024-09-01
出版者
American Chemical Society
収録物名
Journal of the American Chemical Society
巻(号)
146(36)
ページ
25263-25269
抄録
Martensitic transformation with volume expansion plays a crucial role in enhancing the mechanical properties of steel and partially stabilized zirconia. We believe that a similar concept could be applied to unexplored nonoxide materials. Herein, we report the stress-induced martensitic transformation of monoclinic Na3YCl6 with an ∼3.4% expansion. In situ synchrotron X-ray diffraction and atomistic simulations showed that anisotropic crystallographic transformation from monoclinic to rhombohedral Na3YCl6 occurs exclusively under uniaxial pressure; no effect is observed under hydrostatic pressure conditions. The uniaxially pressed powder compact of monoclinic Na3YCl6 showed a large indentation impression and low Young’s modulus, in contrast to its high bulk modulus, suggesting that these unique mechanical properties are induced by the martensitic transformation.
資源タイプ
学術雑誌論文
出版タイプ
Accepted Manuscript
権利情報
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-ZWAF9QPFNUQKJTIGKNSR
PISSN
0002-7863
EISSN
1520-5126
関連情報
PMID
39219155
関連情報 (isVersionOf)
出版社版DOI
https://doi.org/10.1021/jacs.4c09476