Oxyamination of alkenes enabled by direct photoexcitation of fluorenone oxime derivatives

Tagata, Asa; Sawamura, Masaya; Shimizu, Yohei

Oxyamination of alkenes enabled by direct photoexcitation of fluorenone oxime derivatives

Tagata, Asa; Sawamura, Masaya; Shimizu, Yohei

Chemistry letters, 2024, 53(12)

Permalink : https://hdl.handle.net/2115/97334

このアイテムのアクセス数:46件（2026-10-15 09:10 集計）

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論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/97334
タイトル	Oxyamination of alkenes enabled by direct photoexcitation of fluorenone oxime derivatives
著者	Tagata, Asa ; Sawamura, Masaya ; Shimizu, Yohei
著者名 Tagata, Asa
e-Rad_Researcher 40202105 著者名 Sawamura, Masaya
e-Rad_Researcher 60609816 著者名 Shimizu, Yohei
言語	英語
キーワード	alkene
	aminoalcohol
	photoexcitation
発行日	2024-12
出版者	Oxford University Press
収録物名	Chemistry letters
巻(号)	53(12)
抄録	Visible-light-induced oxyamination of alkenes was developed using fluorenone oxime carbonate as a photoactivatable agent. The nitrogen atom was selectively incorporated at the internal position, constructing a sterically congested alpha-tertiary amine moiety. The reaction proceeded without any photocatalyst and in the presence of various additives with different functional groups, highlighting the simplicity and robustness of the protocol. Moreover, the fluorenone oxime motif proved effective for visible-light-induced decarboxylative carboamination and diamination of alkenes.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This is a pre-copyedited, author-produced version of an article accepted for publication in Chemistry letters following peer review. The version of record Oxyamination of alkenes enabled by direct photoexcitation of fluorenone oxime derivatives is available online at: https://doi.org/10.1093/chemle/upae216.
PISSN	0366-7022
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1093/chemle/upae216