Decarbonylation through Aldehydic C–H Bond Cleavage by a Cationic Iridium Catalyst


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/77810

Title:	Decarbonylation through Aldehydic C–H Bond Cleavage by a Cationic Iridium Catalyst
Authors:	Shirai, Tomohiko Browse this author
	Sugimoto, Kazuki Browse this author
	Iwasaki, Masaya Browse this author
	Sumida, Ryuki Browse this author
	Fujita, Harunori Browse this author
	Yamamoto, Yasunori Browse this author →KAKEN DB
Keywords:	decarbonylation
	iridium catalysis
	aldehydes
	C–H bond cleavage
	asymmetric catalysis
	hydroacylation
Issue Date:	May-2019
Publisher:	Georg Thieme
Journal Title:	Synlett
Volume:	30
Issue:	08
Start Page:	972
End Page:	976
Publisher DOI:	10.1055/s-0037-1611802
Abstract:	We report the decarbonylation of aldehydes through an aldehydic C–H bond cleavage catalyzed by a cationic iridium/bisphosphine catalyst. The reaction proceeds under relatively mild conditions to give the corresponding hydrocarbon products in moderate to high yields. In addition, this cationic iridium catalyst system can be applied to an asymmetric hydroacylation of ketones.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/77810
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本靖典

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