Unique [core+two] structure and optical property of a dodeca-ligated undecagold cluster : critical contribution of the exo gold atoms to the electronic structure

Shichibu, Yukatsu; Kamei, Yutaro; Konishi, Katsuaki

Chemical Communications, 2012, 48(61), 7559-7561

Permalink : https://hdl.handle.net/2115/52107

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アクセス権	open access
URI	https://hdl.handle.net/2115/52107
タイトル	Unique [core+two] structure and optical property of a dodeca-ligated undecagold cluster : critical contribution of the exo gold atoms to the electronic structure
著者	Shichibu, Yukatsu ; Kamei, Yutaro ; Konishi, Katsuaki
著者名 Shichibu, Yukatsu
著者名 Kamei, Yutaro
e-Rad_Researcher 80234798 著者名 Konishi, Katsuaki
言語	英語
発行日	2012-08-07
出版者	Royal Society of Chemistry
収録物名	Chemical Communications
巻(号)	48(61)
ページ	7559-7561
抄録	A novel dodeca-ligated undecagold cluster having a nonagold core plus two exo-attached gold atoms was synthesized. Unlike the conventional icosahedron-based "core-only" isomer, the [9+2] cluster showed an intense visible absorption band. Theoretical calculation showed the involvement of the exo gold atoms in the generation of the unique electronic structure.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	Chem. Commun., 2012,48, 7559-7561 - Reproduced by permission of The Royal Society of Chemistry (RSC)
PISSN	1359-7345
関連情報	PMID 22430877
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1039/c2cc30251a