Ring-opening polymerization of a 2,3-disubstituted oxirane leading to a polyether having a carbonyl-aromatic pi-stacked structure

Merlani, Maia; Koyama, Yasuhito; Sato, Hiroyasu et al.

Polymer Chemistry, 2015, 6(11), 1932-1936

Permalink : https://hdl.handle.net/2115/60474

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アクセス権	open access
URI	https://hdl.handle.net/2115/60474
タイトル	Ring-opening polymerization of a 2,3-disubstituted oxirane leading to a polyether having a carbonyl-aromatic pi-stacked structure
著者	Merlani, Maia ; Koyama, Yasuhito ; Sato, Hiroyasu ; Geng, Li ; Barbakadze, Vakhtang ; Chankvetadze, Bezhan ; Nakano, Tamaki
著者名 Merlani, Maia
e-Rad_Researcher 10456262 著者名 Koyama, Yasuhito
著者名 Sato, Hiroyasu
著者名 Geng, Li
著者名 Barbakadze, Vakhtang
著者名 Chankvetadze, Bezhan
e-Rad_Researcher 40227856 著者名 Nakano, Tamaki
言語	英語
発行日	2015-01-16
出版者	Royal Soc Chemistry
収録物名	Polymer Chemistry
巻(号)	6(11)
ページ	1932-1936
抄録	2-Methoxycarbonyl-3-(3,4-dimethoxyphenyl) oxirane was synthesized and polymerized using a cationic initiator to afford a polymer having a rather stiff, stretched conformation. The side-chain methoxycarbonyl group and 3,4-dimethoxyphenyl group of neighboring monomeric units may form a hetero pi-stacked structure between side-chain carbonyl and aromatic groups which leads to intramolecular charge transfer (ICT) interactions. 2-Ethoxy-carbonyl- 3-phenyloxirane failed in polymerization, leading only to small molecules including cyclic compounds.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	© The Royal Society of Chemistry 2015
PISSN	1759-9954
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1039/c4py01711k