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アクセス権	open access
URI	https://hdl.handle.net/2115/74598
タイトル	A Copper(I)-Catalyzed Enantioselective -Boryl Substitution of Trifluoromethyl-Substituted Alkenes: Synthesis of Enantioenriched gamma,gamma-gem-Difluoroallylboronates
著者	Kojima, Ryoto ; Akiyama, Sota ; Ito, Hajime
著者名 Kojima, Ryoto
著者名 Akiyama, Sota
e-Rad_Researcher 90282300 著者名 Ito, Hajime
言語	英語
キーワード	asymmetric catalysis
	boron
	copper
	fluorine
	synthetic methods
発行日	2018-06-11
出版者	Wiley-Blackwell
収録物名	Angewandte chemie-international edition
巻(号)	57(24)
ページ	7196-7199
抄録	The first catalytic enantioselective -boryl substitution of CF3-substituted alkenes is reported. A series of CF3-substituted alkenes was treated with a diboron reagent in the presence of a copper(I)/Josiphos catalyst to afford the corresponding optically active ,-gem-difluoroallylboronates in high enantioselectivity. The thus obtained products could be readily converted into the corresponding difluoromethylene-containing homoallylic alcohols using highly stereospecific allylation reactions.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This is the peer reviewed version of the following article: Angewandte chemie-international edition 57　(24) pp.7196-7199 2018-06-11, which has been published in final form at https://doi.org/10.1002/anie.201803663. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
PISSN	1433-7851
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1002/anie.201803663

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