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Preparation and optical properties of amorphous silica doped with porphins, TCPP

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タイトル: Preparation and optical properties of amorphous silica doped with porphins, TCPP
著者: Uo, Motohiro 著作を一覧する
Yamana, Mitsuharu 著作を一覧する
Soga, Kohei 著作を一覧する
Inoue, Hiroyuki 著作を一覧する
Makishima, Akio 著作を一覧する
キーワード: TCPP
sol-gel process
photochemical hole burning(PHB)
aminopropyltriethoxysilane(APTES)
FT-IR
cross-link
hole width
quantum efficiency
irreversible broadening
発行日: 1997年10月
出版者: SPIE-The International Society for Optical Engineering
誌名: Proceedings of SPIE
巻: 3136
開始ページ: 2
終了ページ: 9
抄録: Tetrakis(4-carboxyphenyl)porphine (TCPP), which is well known as a photochemical hole burning (PHB) dye, was incorporated in amorphous silica materials (a-SiO2) by a sol-gel process with using tetramethoxysilane (TMOS) and aminopropyltriethoxysilane (APTES). With using APTES as precursor of silica gel, TCPP was cross-linked to a-SiO2 matrix through aminopropyl group of APTES. The cross-linkage of TCPP and APTES was confirmed by the FT-IR measurement. The TCPP incorporated in a-SiO2 matrices showed activity in PHB. In the TCPP cross-linked a-SiO2, properties of photochemical hole, such as hole width, quantum efficiency and irreversible broadening under cycle annealing experiment, were improved. A burnt hole at 3.6 K was observed after cycle annealing experiment up to 80 K in the TCPP cross-linked a- SiO2.
記述: Sol-Gel Optics IV
資料タイプ: article (author version)
URI: http://hdl.handle.net/2115/16989
出現コレクション:雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

提供者: 宇尾 基弘

 

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