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Internal-energy measurements of angle-resolved product CO2 in catalytic CO oxidation by means of infrared chemiluminescence.

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Title: Internal-energy measurements of angle-resolved product CO2 in catalytic CO oxidation by means of infrared chemiluminescence.
Authors: Yamanaka, Toshiro Browse this author →KAKEN DB
Matsushima, Tatsuo Browse this author →KAKEN DB
Issue Date: Mar-2007
Publisher: American Institute of Physics
Journal Title: Review of Scientific Instruments
Volume: 78
Issue: 3
Start Page: 034105
Publisher DOI: 10.1063/1.2715931
PMID: 17411200
Abstract: Measurements of both vibrational and rotational energies of product CO2 in CO oxidation on palladium surfaces have been successfully performed as a function of the desorption angle by means of infrared chemiluminescence. The remarkable angle dependences of both energies indicate facile energy partitioning in repulsive desorption and provide new dimensions in the study of surface reaction dynamics as well as additional insights into the product formation site. Details of the apparatus for energy analysis of angle-resolved products are described, especially on how to pick up extremely weak infrared emission signals. ©2007 American Institute of Physics
Rights: Copyright © 2007 American Institute of Physics
Type: article
URI: http://hdl.handle.net/2115/22100
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山中 俊朗

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