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Temperature, composition, and hydrogen isotope effect in the hydrogenation of CO on amorphous ice surface at 10-20 K.

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Title: Temperature, composition, and hydrogen isotope effect in the hydrogenation of CO on amorphous ice surface at 10-20 K.
Authors: Hidaka, H. Browse this author
Kouchi, A. Browse this author →KAKEN DB
Watanabe, N. Browse this author →KAKEN DB
Issue Date: 28-May-2007
Publisher: American Institute of Physics
Journal Title: The Journal of Chemical Physics
Volume: 126
Issue: 20
Start Page: 204707
Publisher DOI: 10.1063/1.2735573
PMID: 17552789
Abstract: An experiment on the addition reaction of a D atom (deuteration) to CO on a cold ice surface is performed by deuterium atom exposure of three types of samples (pure solid CO, CO-capped H2O ice, and CO–H2O mixed ice) at 10–20 K. The variation of IR absorption spectra for the samples was measured by a Fourier transform infrared spectrometer during exposure to deuterium atoms. Reactions on pure solid CO were observed only at 10 K, while reactions on CO-capped H2O ice and CO–H2O mixed ice were observed to proceed even at 20 K. This indicates that the coexistence of H2O at the surface raises the reactive temperature. In addition, the experiment on H atom exposure was also carried out at 15 K to compare the reaction rate constant between the H and D atoms. The ratio of reaction rate constant kD/kH obtained is about 0.08 at 15 K. The authors provide information on the potential energy for the H+CO reaction at the surface by using the ratio kD/kH and by a model calculation of the potential tunneling with the asymmetric Eckart potential.
Rights: Copyright © 2007 American Institute of Physics
Type: article
Appears in Collections:低温科学研究所 (Institute of Low Temperature Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 日高 宏

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