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Cracking of Cellulose over Supported Metal Catalysts

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/32317

Title: Cracking of Cellulose over Supported Metal Catalysts
Authors: Dhepe, Paresh L. Browse this author
Fukuoka, Atsushi Browse this author →KAKEN DB
Keywords: cellulose
sorbitol
supported metal catalyst
biomass
bio-refinery
Issue Date: Dec-2007
Publisher: Springer
Journal Title: Catalysis Surveys from Asia
Volume: 11
Issue: 4
Start Page: 186
End Page: 191
Publisher DOI: 10.1007/s10563-007-9033-1
Abstract: Cellulose is cracked over supported Pt or Ru catalysts under hydrogenolysis conditions in water to give sorbitol as a main product. Among the catalysts tested, Pt/gamma-Al_{2}O_{3} gave the highest yield and selectivity, and this catalyst was recyclable in repeated runs. It is proposed that cellulose is hydrolyzed by in situ generated acid sites to form glucose, and glucose is immediately reduced to sorbitol over the metal catalyst.
Rights: The original publication is available at www.springerlink.com.
Relation: http://www.springerlink.com
Type: article (author version)
URI: http://hdl.handle.net/2115/32317
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 福岡 淳

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