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Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Science / Faculty of Science >
Journal of the Faculty of Science, Hokkaido University. Series 4, Geology and mineralogy >
Vol.XXIII, No.2 >
Partitioning of the Transition Metals Mn, Fe, Co, Ni and Zn between Orthopyroxene and Silicate Melt : Ionic Size Effect to the Partitioning Behavior
| Title: | Partitioning of the Transition Metals Mn, Fe, Co, Ni and Zn between Orthopyroxene and Silicate Melt : Ionic Size Effect to the Partitioning Behavior |
| Authors: | Hashizume, Hideo Browse this author | | Hariya, Yu Browse this author |
| Issue Date: | Aug-1992 |
| Publisher: | 北海道大学 |
| Journal Title: | 北海道大学理学部紀要 |
| Journal Title(alt): | Journal of the Faculty of Science, Hokkaido University. Series 4, Geology and mineralogy |
| Volume: | 23 |
| Issue: | 2 |
| Start Page: | 211 |
| End Page: | 226 |
| Abstract: | Partition coefficients of Mn2+, Fe2+, CO2+, Ni2+, and Zn2+ between orthopyroxene and silicate melt have been determined in the system Mg2SiO4-SiO2-H2O at pressures of 1 and 3 GPa and at a temperature of 1400℃. The partition coefficient was defined by the ratio of the concentration of an element in orthopyroxene to that of the element in silicate melt. Partition coefficients were plotted on a partition coefficient versus ionic radius (PC-IR) diagram. Partition coefficients were linearly related to ionic radii. However, the partition coefficient of Zn deviated from the linear relationship between partition coefficients and ionic radii. This was called the Zn2+ anomaly.
However, a partition coefficient versus metal and oxygen (M-O) distance (PC-MO) diagram was depicted instead of a PC-IR diagram. On a PC-MO diagram, partition coefficients were linearly related to M-O distances. An element with a small M-O distance are concentrated in orthopyroxene. The Zn2+ anomaly disappeared on PC-MO diagrams. The partitioning behavior between a site (an M1 or M2 site) in orthopyroxene and silicate melt was estimated by using the intracrystalline cation distribution data. These partition coefficients were plotted on both a PC-M(1)O diagram and a PC-M(2)O diagram. The element of a small M(1)-O distance was concentrated in orthopyroxene on the PC-M(1)O diagram. The lines were negative gentle slopes for the PC-M(2)O diagram. Partition coefficients between the M2 site in orthopyroxene and silicate melt were not almost dependent on the M(2)-O distance. |
| Type: | bulletin (article) |
| URI: | http://hdl.handle.net/2115/36779 |
| Appears in Collections: | Journal of the Faculty of Science, Hokkaido University. Series 4, Geology and mineralogy > Vol.XXIII, No.2
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