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Synthesis of a tetrasaccharide repeating unit of O-antigenic polysaccharide of Salmonella enteritidis by use of unique and odorless dodecyl thioglycosyl donors

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Title: Synthesis of a tetrasaccharide repeating unit of O-antigenic polysaccharide of Salmonella enteritidis by use of unique and odorless dodecyl thioglycosyl donors
Authors: Son, Sang-Hyun Browse this author
Tano, Chiharu Browse this author
Furuike, Tetsuya Browse this author
Sakairi, Nobuo Browse this author →KAKEN DB
Keywords: lipo polysaccharide
synthesis
glycosylation
Salmonella Enteritidis
リポ多糖
合成
グリコシル化反応
サルモネラ菌
Issue Date: 1-Sep-2008
Publisher: Pergamon Press
Journal Title: Tetrahedron Letters
Volume: 49
Issue: 36
Start Page: 5289
End Page: 5292
Publisher DOI: 10.1016/j.tetlet.2008.06.097
Abstract: The first total synthesis of a unique tetrasaccharide repeating unit of lipopolysaccharide from Salmonella enteritidis has been accomplished by assembly of dodecyl thioglycosides. The crucial key steps were preparation of a rare branched dideoxy sugar, D-tyvelose (3,6-dideoxy-D-arabino-D-hexose) and sequential regioselective glycosylation at 2,3-positions of a central D-mannose residue 5 with D-tyvelose 6 and D-galactose donors 7.
Type: article (author version)
URI: http://hdl.handle.net/2115/38356
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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