Pre-activation of fully acetylated dodecyl thioglycosides with BSP-Tf2O led to efficient glycosylation at low temperature


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/38387

Title:	Pre-activation of fully acetylated dodecyl thioglycosides with BSP-Tf2O led to efficient glycosylation at low temperature
Authors:	Son, Sang-Hyun Browse this author
	Tano, Chiharu Browse this author
	Furuike, Tetsuya Browse this author
	Sakairi, Nobuo Browse this author →KAKEN DB
Keywords:	Dodecyl thioglycoside
	1-Dodecanethiol
	Glycosylation
	Oligosaccharide
	Synthesis
	グリコシル化反応
	合成
	オリゴ糖
	ドデシルチオグリコシド
Issue Date:	17-Feb-2009
Publisher:	Elsevier
Journal Title:	Carbohydrate research
Volume:	344
Issue:	3
Start Page:	285
End Page:	290
Publisher DOI:	10.1016/j.carres.2008.11.008
PMID:	19070835
Abstract:	Fully acetylated dodecyl thioglycosides found to be used as glycosyl donors by activation with 1.benzenesulfinyl piperidine (BSP) and triflic anhydride (Tf2O) at -78℃, and the glycosyl acceptor was added to the reaction mixture at the same temperature to furnish various disaccharides and Lewis a (Le^a) trisaccharide in good yields.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/38387
Appears in Collections:	環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 坂入信夫

OAI-PMH ( junii2 , jpcoar_1.0 )

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