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Pre-activation of fully acetylated dodecyl thioglycosides with BSP-Tf2O led to efficient glycosylation at low temperature

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/38387

Title: Pre-activation of fully acetylated dodecyl thioglycosides with BSP-Tf2O led to efficient glycosylation at low temperature
Authors: Son, Sang-Hyun Browse this author
Tano, Chiharu Browse this author
Furuike, Tetsuya Browse this author
Sakairi, Nobuo Browse this author →KAKEN DB
Keywords: Dodecyl thioglycoside
1-Dodecanethiol
Glycosylation
Oligosaccharide
Synthesis
グリコシル化反応
合成
オリゴ糖
ドデシルチオグリコシド
Issue Date: 17-Feb-2009
Publisher: Elsevier
Journal Title: Carbohydrate research
Volume: 344
Issue: 3
Start Page: 285
End Page: 290
Publisher DOI: 10.1016/j.carres.2008.11.008
PMID: 19070835
Abstract: Fully acetylated dodecyl thioglycosides found to be used as glycosyl donors by activation with 1.benzenesulfinyl piperidine (BSP) and triflic anhydride (Tf2O) at -78℃, and the glycosyl acceptor was added to the reaction mixture at the same temperature to furnish various disaccharides and Lewis a (Le^a) trisaccharide in good yields.
Type: article (author version)
URI: http://hdl.handle.net/2115/38387
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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