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A potential glucuronate glycosyl donor with 2-O-acyl-6,3-lactone structure: efficient synthesis of glycosaminoglycan disaccharides

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Title: A potential glucuronate glycosyl donor with 2-O-acyl-6,3-lactone structure: efficient synthesis of glycosaminoglycan disaccharides
Authors: Furukawa, Takayuki Browse this author
Hinou, Hiroshi Browse this author →KAKEN DB
Shimawaki, Ken Browse this author
Nishimura, Shin-Ichiro Browse this author
Keywords: Glycosylation
Lactones
Carbohydrate
Glycosaminoglycans
1,2-trans Stereoselectivity
Issue Date: 26-Oct-2011
Publisher: Elsevier
Journal Title: Tetrahedron Letters
Volume: 52
Issue: 43
Start Page: 5567
End Page: 5570
Publisher DOI: 10.1016/j.tetlet.2011.08.024
Abstract: Development of β-selective glucuronylation reaction using phenyl 2,4-di-O-acetyl-1-thio-β-D-glucopyranosidurono-6,3-lactone was described. Glycosylations of this glycosyl donor with hexosamine derivatives proceeded with excellent yield and β-stereoselectivity to afford glycosaminoglycan-type disaccharides.
Type: article (author version)
URI: http://hdl.handle.net/2115/47554
Appears in Collections:生命科学院・先端生命科学研究院 (Graduate School of Life Science / Faculty of Advanced Life Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 比能 洋

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