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Catalysis and characterization of carbon-supported ruthenium for cellulose hydrolysis

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Title: Catalysis and characterization of carbon-supported ruthenium for cellulose hydrolysis
Authors: Komanoya, Tasuku Browse this author
Kobayashi, Hirokazu Browse this author
Hara, Kenji Browse this author
Chun, Wang-Jae Browse this author
Fukuoka, Atsushi Browse this author →KAKEN DB
Keywords: Biomass
Cellulose
Hydrolysis
Glucose
Supported Ru catalyst
Hydrous ruthenium oxide
Issue Date: 4-Nov-2011
Publisher: Elsevier B.V.
Journal Title: Applied Catalysis A: General
Volume: 407
Issue: 1-2
Start Page: 188
End Page: 194
Publisher DOI: 10.1016/j.apcata.2011.08.039
Abstract: Ru catalyst supported on mesoporous carbon CMK-3 shows high activity and durability for the hydrolysis of cellulose to glucose in hot compressed water at 503 K. The Ru/CMK-3 catalyst also hydrolyzes cellobiose to glucose in water at 393 K. Several physicochemical methods such as XRD, TEM, XPS, H2-TPR, O2-titration, and XAFS were used to characterize active Ru species on CMK-3 and to clarify the formation pathway of the active species. From these studies, we conclude that hydrous Ru oxide RuO2・2H2O is formed on CMK-3 after H2-reduction of RuCl3/CMK-3 at 673 K and subsequent passivation at room temperature, and that the Ru oxide nanoparticles with a mean diameter of 1.1 nm are highly dispersed on CMK-3.
Type: article (author version)
URI: http://hdl.handle.net/2115/47764
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 福岡 淳

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