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Isolation and structural characterization of magic silver clusters protected by 4-(tert-butyl)benzyl mercaptan

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Title: Isolation and structural characterization of magic silver clusters protected by 4-(tert-butyl)benzyl mercaptan
Authors: Negishi, Yuichi Browse this author
Arai, Rio Browse this author
Niihori, Yoshiki Browse this author
Tsukuda, Tatsuya Browse this author →KAKEN DB
Issue Date: 28-May-2011
Publisher: Royal Society of Chemistry
Journal Title: Chemical Communications
Volume: 47
Issue: 20
Start Page: 5693
End Page: 5695
Publisher DOI: 10.1039/c0cc05587e
Abstract: Small silver clusters (average diameter of 1.2 nm) protected by 4-(tert-butyl)benzyl mercaptan (BBSH) were converted to stable, monodisperse clusters (2.1 nm) by a ripening process with excess amount of BBSH. Multiple characterizations of the isolated magic clusters revealed an approximate chemical composition of Ag∼280(SBB)∼120.
Rights: Chem. Commun., 2011, 47, 5693-5695 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type: article (author version)
URI: http://hdl.handle.net/2115/49263
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 佃 達哉

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