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The rates of sea salt sulfatization in the atmosphere and surface snow of inland Antarctica
| Title: | The rates of sea salt sulfatization in the atmosphere and surface snow of inland Antarctica |
| Authors: | Iizuka, Yoshinori Browse this author →KAKEN DB | | Tsuchimoto, Akira Browse this author | | Hoshina, Yu Browse this author | | Sakurai, Toshimitsu Browse this author | | Hansson, Margareta Browse this author | | Karlin, Torbjörn Browse this author | | Fujita, Koji Browse this author | | Nakazawa, Fumio Browse this author | | Motoyama, Hideaki Browse this author | | Fujita, Shuji Browse this author |
| Issue Date: | 28-Feb-2012 |
| Publisher: | American Geophysical Union |
| Journal Title: | Journal of Geophysical Research, Atmospheres |
| Volume: | 117 |
| Start Page: | D04308 |
| Publisher DOI: | 10.1029/2011JD016378 |
| Abstract: | Most of the aerosol particles present in the surface snow and ice of inland Antarctica come from primary sea salt (sodium chloride) and marine biological activity (methansulfonic and sulfuric acids). Melted water from surface snow, firn, and Holocene ice contains mainly sodium, chloride, and sulfate ions. Although it is well known that sea salt aerosols react rapidly with sulfuric acid, a process known as sulfatization, it is not known when this process takes place. In this research we undertake to measure the proportion of sea salt aerosols that undergo sulfatization in the atmosphere and surface snow, as opposed to deeper ice, in order to understand the suitability of sea salt aerosols as a proxy for past climates in deep ice cores. We directly measure the sulfatization rates in recently fallen snow (0-4 m in depth) collected at the Dome Fuji station, using X-ray dispersion spectroscopy to determine the constituent elements of soluble particles and computing the molar ratios of sodium chloride and sodium sulfate. We estimate that about 90% of the initial sea salt aerosols sulfatize as they are taken up by precipitation over Dome Fuji or in the snowpack within one year after being deposited on the ice sheet. |
| Rights: | Copyright 2012 by the American Geophysical Union. |
| Type: | article |
| URI: | http://hdl.handle.net/2115/49886 |
| Appears in Collections: | 低温科学研究所 (Institute of Low Temperature Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 飯塚 芳徳
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