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Diurnal variations of organic molecular tracers and stable carbon isotopic composition in atmospheric aerosols over Mt. Tai in the North China Plain: an influence of biomass burning

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Title: Diurnal variations of organic molecular tracers and stable carbon isotopic composition in atmospheric aerosols over Mt. Tai in the North China Plain: an influence of biomass burning
Authors: Fu, P. Q. Browse this author
Kawamura, K. Browse this author →KAKEN DB
Chen, J. Browse this author
Li, J. Browse this author
Sun, Y. L. Browse this author
Liu, Y. Browse this author
Tachibana, E. Browse this author
Aggarwal, S. G. Browse this author
Okuzawa, K. Browse this author
Tanimoto, H. Browse this author
Kanaya, Y. Browse this author
Wang, Z. F. Browse this author
Issue Date: 18-Sep-2012
Publisher: Copernicus Publications
Journal Title: Atmospheric Chemistry and Physics
Volume: 12
Issue: 18
Start Page: 8359
End Page: 8375
Publisher DOI: 10.5194/acp-12-8359-2012
Abstract: Organic tracer compounds, as well as organic carbon (OC), elemental carbon (EC), water-soluble organic carbon (WSOC), and stable carbon isotope ratios (δ13C) of total carbon (TC) have been investigated in aerosol samples collected during early and late periods of the Mount Tai eXperiment 2006 (MTX2006) field campaign in the North China Plain. Total solvent-extractable fractions were investigated by gas chromatography/mass spectrometry. More than 130 organic compounds were detected in the aerosol samples. They were grouped into twelve organic compound classes, including biomass burning tracers, biogenic primary sugars, biogenic secondary organic aerosol (SOA) tracers, and anthropogenic tracers such as phthalates, hopanes and polycyclic aromatic hydrocarbons (PAHs). In early June when the field burning activities of wheat straws in the North China Plain were very active, the total identified organics (2090 ± 1170 ng m^[-3]) were double those in late June (926 ± 574 ng m^[-3]). All the compound classes were more abundant in early June than in late June, except phthalate esters, which were higher in late June. Levoglucosan (88-1210 ng m^[-3], mean 403 ng m^[-3]) was found as the most abundant single compound in early June, while diisobutyl phthalate was the predominant species in late June. During the biomass-burning period in early June, the diurnal trends of most of the primary and secondary organic aerosol tracers were characterized by the concentration peaks observed at mid-night or in early morning, while in late June most of the organic species peaked in late afternoon. This suggests that smoke plumes from biomass burning can uplift the aerosol particulate matter to a certain altitude, which could be further transported to and encountered the summit of Mt. Tai during nighttime. On the basis of the tracer-based method for the estimation of biomass-burning OC, fungal-spore OC and biogenic secondary organic carbon (SOC), we estimate that an average of 24% (up to 64 %) of the OC in the Mt. Tai aerosols was due to biomass burning in early June, followed by the contribution of isoprene SOC (mean 4.3 %). In contrast, isoprene SOC was the main contributor (6.6 %) to OC, and only 3.0% of the OC was due to biomass burning in late June. In early June, δ13C of TC (-26.6 to -23.2 ‰, mean -25.0 ‰) were lower than those (-23.9 to -21.9 ‰, mean -22.9 ‰) in late June. In addition, a strong anti-correlation was found between levoglucosan and δ13C values. This study demonstrates that crop-residue burning activities can significantly enhance the organic aerosol loading and alter the organic composition and stable carbon isotopic composition of aerosol particles in the troposphere over the North China Plain.
Type: article
Appears in Collections:低温科学研究所 (Institute of Low Temperature Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 河村 公隆

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