Operando Observation of Ni2P Structural Changes during Catalytic Reaction: Effect of H2S Pretreatment


Hokkaido University \| Library \| HUSCAP	Advanced Search		言語

	Home
	About HUSCAP
	Open Access Policy

	Browse by Author

Browse
	Communities & Collections

	Scholarly Journals
	Theses
	Doctoral Dissertations Listed by Graduate Schools
	Conference Procs.
	Events

	HUSCAP Senior (in Japanese)

	Societies

	Downloads (country)

For university staff
	How to post your papers to HUSCAP
	Publication of theses
	Helpline about theses publication

Open Archives Compliant

You can search our collection also at:
	Google
	Google Scholar
	CiNii
	IRDB
	OAIster
	NDLTD

Files in This Item:

CL41-10_1238-1240.pdf

349.28 kB

PDF

Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/50902

Title:	Operando Observation of Ni2P Structural Changes during Catalytic Reaction: Effect of H2S Pretreatment
Authors:	Wada, Takahiro Browse this author
	Bando, Kyoko K. Browse this author
	Oyama, S. Ted Browse this author
	Miyamoto, Takeshi Browse this author
	Takakusagi, Satoru Browse this author →KAKEN DB
	Asakura, Kiyotaka Browse this author →KAKEN DB
Issue Date:	Oct-2012
Publisher:	Chemical Society of Japan
Journal Title:	Chemistry Letters
Volume:	41
Issue:	10
Start Page:	1238
End Page:	1240
Publisher DOI:	10.1246/cl.2012.1238
Abstract:	In situ X-ray absorption spectroscopy was used to study the effect of H2S pretreatment on the activation of Ni2P catalysts for the thiophene hydrodesulfurization (HDS) reaction. It was found that H2S treatment produced Ni-S bonds that were slightly longer and that had higher coordination numbers than those formed during reaction. The longer Ni-S bonds formed by H2S treatment were changed to the shorter Ni-S bonds by the catalytic reaction, and these shorter bonds were associated with high activity. The work provides evidence that a NiPS phase is active in the HDS reaction.
Type:	article
URI:	http://hdl.handle.net/2115/50902
Appears in Collections:	触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 朝倉清高

OAI-PMH ( junii2 , jpcoar_1.0 )

- Hokkaido University