Unique [core+two] structure and optical property of a dodeca-ligated undecagold cluster : critical contribution of the exo gold atoms to the electronic structure


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/52107

Title:	Unique [core+two] structure and optical property of a dodeca-ligated undecagold cluster : critical contribution of the exo gold atoms to the electronic structure
Authors:	Shichibu, Yukatsu Browse this author
	Kamei, Yutaro Browse this author
	Konishi, Katsuaki Browse this author →KAKEN DB
Issue Date:	7-Aug-2012
Publisher:	Royal Society of Chemistry
Journal Title:	Chemical Communications
Volume:	48
Issue:	61
Start Page:	7559
End Page:	7561
Publisher DOI:	10.1039/c2cc30251a
PMID:	22430877
Abstract:	A novel dodeca-ligated undecagold cluster having a nonagold core plus two exo-attached gold atoms was synthesized. Unlike the conventional icosahedron-based "core-only" isomer, the [9+2] cluster showed an intense visible absorption band. Theoretical calculation showed the involvement of the exo gold atoms in the generation of the unique electronic structure.
Rights:	Chem. Commun., 2012,48, 7559-7561 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type:	article (author version)
URI:	http://hdl.handle.net/2115/52107
Appears in Collections:	環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 小西克明

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