Simultaneous formation of sorbitol and gluconic acid from cellobiose using carbon-supported ruthenium catalysts


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/53091

Title:	Simultaneous formation of sorbitol and gluconic acid from cellobiose using carbon-supported ruthenium catalysts
Authors:	Komanoya, Tasuku Browse this author
	Kobayashi, Hirokazu Browse this author
	Hara, Kenji Browse this author
	Chun, Wang-Jae Browse this author
	Fukuoka, Atsushi Browse this author →KAKEN DB
Keywords:	cellobiose
	supported ruthenium catalyst
	hydrolysis
	disproportionation
Issue Date:	Mar-2013
Publisher:	Elsevier
Journal Title:	Journal of Energy Chemistry
Volume:	22
Issue:	2
Start Page:	290
End Page:	295
Publisher DOI:	10.1016/S2095-4956(13)60035-2
Abstract:	A carbon-supported Ru catalyst, Ru/BP2000, is able to simultaneously convert cellobiose into sorbitol and gluconic acid. This reaction occurs as the result of hydrolytic disproportionation in water at 393 K under an Ar atmosphere, without bases or sacrificial reagents. In-situ XANES measurements suggest that the active Ru species involved is composed of partially oxidized Ru metal.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/53091
Appears in Collections:	触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 福岡淳

OAI-PMH ( junii2 , jpcoar_1.0 )

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