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Exciton Chirality Method in Vibrational Circular Dichroism

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Title: Exciton Chirality Method in Vibrational Circular Dichroism
Authors: Taniguchi, Tohru Browse this author →KAKEN DB
Monde, Kenji Browse this author →KAKEN DB
Issue Date: 2-Feb-2012
Publisher: American Chemical Society
Journal Title: Journal of the American Chemical Society
Volume: 134
Issue: 8
Start Page: 3695
End Page: 3698
Publisher DOI: 10.1021/ja3001584
PMID: 22299596
Abstract: The interaction of two IR chromophores yields a strong vibrational circular dichroism couplet whose sign reflects the absolute configuration of the molecule. We present a method to determine absolute configuration of a chiral molecule based on this couplet without need of theoretical calculation. Not only can this method analyze various molecules whose absolute configuration is difficult to determine by other spectroscopic methods, but also it can significantly enhance VCD signals.
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/ja3001584.
Type: article (author version)
URI: http://hdl.handle.net/2115/53393
Appears in Collections:生命科学院・先端生命科学研究院 (Graduate School of Life Science / Faculty of Advanced Life Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 門出 健次

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