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Exciton Chirality Method in Vibrational Circular Dichroism
| Title: | Exciton Chirality Method in Vibrational Circular Dichroism |
| Authors: | Taniguchi, Tohru Browse this author →KAKEN DB | | Monde, Kenji Browse this author →KAKEN DB |
| Issue Date: | 2-Feb-2012 |
| Publisher: | American Chemical Society |
| Journal Title: | Journal of the American Chemical Society |
| Volume: | 134 |
| Issue: | 8 |
| Start Page: | 3695 |
| End Page: | 3698 |
| Publisher DOI: | 10.1021/ja3001584 |
| PMID: | 22299596 |
| Abstract: | The interaction of two IR chromophores yields a strong vibrational circular dichroism couplet whose sign reflects the absolute configuration of the molecule. We present a method to determine absolute configuration of a chiral molecule based on this couplet without need of theoretical calculation. Not only can this method analyze various molecules whose absolute configuration is difficult to determine by other spectroscopic methods, but also it can significantly enhance VCD signals. |
| Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/ja3001584. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/53393 |
| Appears in Collections: | 生命科学院・先端生命科学研究院 (Graduate School of Life Science / Faculty of Advanced Life Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 門出 健次
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