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Recent progress toward synthesis of chlorosulfolipids: total synthesis and methodology

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Title: Recent progress toward synthesis of chlorosulfolipids: total synthesis and methodology
Authors: Umezawa, Taiki Browse this author
Matsuda, Fuyuhiko Browse this author →KAKEN DB
Keywords: Chlorosulfolipid
Total synthesis
1,2-Dichlorination
Epoxide opening by chloride
Issue Date: 7-May-2014
Publisher: Elsevier
Journal Title: Tetrahedron Letters
Volume: 55
Issue: 19
Start Page: 3003
End Page: 3012
Publisher DOI: 10.1016/j.tetlet.2014.03.082
Abstract: Chlorosulfolipids (CSLs) are an intriguing family of natural products featuring highly chlorinated linear hydrocarbon skeletons. Although CSLs were first isolated in 1962, chemical synthesis of CSLs was hampered because relevant methods for stereoselective construction of the polychlorinated motifs of CSLs were scarce. Since Carreira's first total synthesis of the CSL mytilipin A in 2009, several groups, including our own, have reported total syntheses of CSLs. As a result of these total syntheses, important progress has been made in the development of reliable synthetic methods for stereoselective polychlorination. In this digest, we summarize the total syntheses of CSLs by focusing on synthetic methods for stereoselective polychlorination of the organic frameworks of CSLs.
Rights: © 2014 Published by Elsevier Ltd.
Type: article (author version)
URI: http://hdl.handle.net/2115/56540
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 梅澤 大樹

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